diff --git a/packages/edit-post/src/plugins/index.js b/packages/edit-post/src/plugins/index.js
index c0f3c5264596a0..94a5d4c98396cf 100644
--- a/packages/edit-post/src/plugins/index.js
+++ b/packages/edit-post/src/plugins/index.js
@@ -14,7 +14,6 @@ import CopyContentMenuItem from './copy-content-menu-item';
 import KeyboardShortcutsHelpMenuItem from './keyboard-shortcuts-help-menu-item';
 import ToolsMoreMenuGroup from '../components/header/tools-more-menu-group';
 import WelcomeGuideMenuItem from './welcome-guide-menu-item';
-import NavigationListViewMenuItem from './navigation-list-view-menu-item';
 
 registerPlugin( 'edit-post', {
 	render() {
@@ -56,7 +55,6 @@ registerPlugin( 'edit-post', {
 						</>
 					) }
 				</ToolsMoreMenuGroup>
-				<NavigationListViewMenuItem />
 			</>
 		);
 	},
diff --git a/packages/edit-post/src/plugins/navigation-list-view-menu-item.js b/packages/edit-post/src/plugins/navigation-list-view-menu-item.js
deleted file mode 100644
index 18bb1bed3760ac..00000000000000
--- a/packages/edit-post/src/plugins/navigation-list-view-menu-item.js
+++ /dev/null
@@ -1,56 +0,0 @@
-/**
- * WordPress dependencies
- */
-import {
-	BlockEditorProvider,
-	__unstableBlockToolbarLastItem,
-	__unstableBlockNameContext,
-} from '@wordpress/block-editor';
-import { ToolbarButton, ToolbarGroup } from '@wordpress/components';
-import { useDispatch } from '@wordpress/data';
-import { Fragment } from '@wordpress/element';
-import { __ } from '@wordpress/i18n';
-import { listView } from '@wordpress/icons';
-
-const NavMenuSidebarToggle = () => {
-	// eslint-disable-next-line @wordpress/data-no-store-string-literals
-	const { openGeneralSidebar } = useDispatch( 'core/edit-post' );
-
-	return (
-		<ToolbarGroup>
-			<ToolbarButton
-				className="components-toolbar__control"
-				label={ __( 'Open navigation list view' ) }
-				onClick={ () => openGeneralSidebar( 'edit-post/block' ) }
-				icon={ listView }
-			/>
-		</ToolbarGroup>
-	);
-};
-
-let MaybeNavMenuSidebarToggle = Fragment;
-
-const isOffCanvasNavigationEditorEnabled =
-	window?.__experimentalEnableOffCanvasNavigationEditor === true;
-
-if ( isOffCanvasNavigationEditorEnabled ) {
-	MaybeNavMenuSidebarToggle = NavMenuSidebarToggle;
-}
-
-const NavigationEditMenuItem = () => {
-	return (
-		<BlockEditorProvider>
-			<__unstableBlockToolbarLastItem>
-				<__unstableBlockNameContext.Consumer>
-					{ ( blockName ) =>
-						blockName === 'core/navigation' && (
-							<MaybeNavMenuSidebarToggle />
-						)
-					}
-				</__unstableBlockNameContext.Consumer>
-			</__unstableBlockToolbarLastItem>
-		</BlockEditorProvider>
-	);
-};
-
-export default NavigationEditMenuItem;
diff --git a/packages/edit-site/src/components/block-editor/index.js b/packages/edit-site/src/components/block-editor/index.js
index fc09b957a3cd28..a237ce8f329202 100644
--- a/packages/edit-site/src/components/block-editor/index.js
+++ b/packages/edit-site/src/components/block-editor/index.js
@@ -7,7 +7,7 @@ import classnames from 'classnames';
  * WordPress dependencies
  */
 import { useSelect, useDispatch } from '@wordpress/data';
-import { useCallback, useMemo, useRef, Fragment } from '@wordpress/element';
+import { useCallback, useMemo, useRef } from '@wordpress/element';
 import {
 	useEntityBlockEditor,
 	__experimentalFetchMedia as fetchMedia,
@@ -19,12 +19,10 @@ import {
 	__experimentalLinkControl,
 	BlockInspector,
 	BlockTools,
-	__unstableBlockToolbarLastItem,
 	__unstableUseClipboardHandler as useClipboardHandler,
 	__unstableUseTypingObserver as useTypingObserver,
 	BlockEditorKeyboardShortcuts,
 	store as blockEditorStore,
-	__unstableBlockNameContext,
 } from '@wordpress/block-editor';
 import {
 	useMergeRefs,
@@ -32,9 +30,6 @@ import {
 	useResizeObserver,
 } from '@wordpress/compose';
 import { ReusableBlocksMenuItems } from '@wordpress/reusable-blocks';
-import { listView } from '@wordpress/icons';
-import { ToolbarButton, ToolbarGroup } from '@wordpress/components';
-import { __ } from '@wordpress/i18n';
 
 /**
  * Internal dependencies
@@ -159,33 +154,6 @@ export default function BlockEditor( { setIsInserterOpen } ) {
 	const showBlockAppender =
 		( isTemplatePart && hasBlocks ) || isViewMode ? false : undefined;
 
-	// eslint-disable-next-line @wordpress/data-no-store-string-literals
-	const { enableComplementaryArea } = useDispatch( 'core/interface' );
-
-	const NavMenuSidebarToggle = () => (
-		<ToolbarGroup>
-			<ToolbarButton
-				className="components-toolbar__control"
-				label={ __( 'Open navigation list view' ) }
-				onClick={ () =>
-					enableComplementaryArea(
-						'core/edit-site',
-						'edit-site/block-inspector'
-					)
-				}
-				icon={ listView }
-			/>
-		</ToolbarGroup>
-	);
-
-	let MaybeNavMenuSidebarToggle = Fragment;
-	const isOffCanvasNavigationEditorEnabled =
-		window?.__experimentalEnableOffCanvasNavigationEditor === true;
-
-	if ( isOffCanvasNavigationEditorEnabled ) {
-		MaybeNavMenuSidebarToggle = NavMenuSidebarToggle;
-	}
-
 	return (
 		<BlockEditorProvider
 			settings={ settings }
@@ -252,15 +220,6 @@ export default function BlockEditor( { setIsInserterOpen } ) {
 									/>
 								</EditorCanvas>
 							</ResizableEditor>
-							<__unstableBlockToolbarLastItem>
-								<__unstableBlockNameContext.Consumer>
-									{ ( blockName ) =>
-										blockName === 'core/navigation' && (
-											<MaybeNavMenuSidebarToggle />
-										)
-									}
-								</__unstableBlockNameContext.Consumer>
-							</__unstableBlockToolbarLastItem>
 						</BlockTools>
 					)
 				}